Resources: 1M hydrochloric acid, pipette, metal sample: magnesium, iron, lead, zinc, aluminium, splint, candle matches, test tubes and rack and a boiling tube.
Core Handout: Card cut-outs to accompany the 'Making Salts' activity and instructions for the reactivity activity.
Ensure that students have a good understanding of the properties of metals and non-metals, including their physical properties, reactivity and conductivity. Prior knowledge of the properties of acids and bases, including pH, can be helpful in understanding the reactions of acids with metals.
Recap the previous lesson on neutralisation reactions, focusing on the concept of acids and their properties. Ask the students to identify and write down the definition of a metal. Review the concept of chemical reactions and how they occur.
Introduce the concept of acid-metal reactions and explain how they occur. Provide examples of acid-metal reactions, including the reaction of hydrochloric acid with magnesium and iron. Demonstrate the experiment to observe the reaction of magnesium and iron with hydrochloric acid, step by step. Explain how to write the word equation for the reaction of hydrochloric acid with magnesium and iron, and the balanced chemical equation for the reaction with magnesium. Allow students to work in pairs to carry out the experiment using the magnesium and iron provided, and record their observations and results. Discuss the results and explain the products of the reaction of magnesium and iron with hydrochloric acid. Reinforce the importance of safety precautions when working with chemicals.
Career Film: Anna works as a Graduate Programmes Consultant as part of the Human Resources Team for BP.
Expert Film: Watch Heather and Sam produce some hydrogen-filled bubbles through the reaction of a metal and an acid.
Acids and Metals
The students will be comparing the reactivity of different metals with acid.
Student Method
Once completed, rank the metals in order of reactivity, justifying your order.
Making salts card sort
Cut out the acid and metal cards from the handout. Make one pile for the metals and one pile for the acids with the writing face down. Shuffle the piles and then randomly select a piece of paper from each pile and, as quickly as possible, name the salt that would be formed. To extend this task, the students could also write down the balanced chemical equation for the reaction between the randomly chosen metal and salt.
This could also be done competitively in larger groups/teams with a simple scoring system for fastest to name the salt formed.
Support:
Stretch:
Challenge:
Ask the students to share their observations and results from the experiment. Review the learning objectives and ask students to reflect on whether they have achieved them. Preview the next lesson on acid-base titrations, which will build on the concepts learned in this lesson.
For the reaction of an acid and a metal we would expect there to be heat released (this is a physical change for the reaction and could be measured using a thermometer). We would also expect to see bubbles forming at the metal surface due to the production of hydrogen gas. How quickly the reaction proceeds (or how vigorously the reaction will bubble) depends on many factors, such as the reactivity of the metal.
For a reaction with a particular acid, an approximate reactivity series for metals is (from most reactive to least reactive): Potassium > Sodium > Calcium > Magnesium > Aluminium > Zinc > Iron > Tin > Lead > Copper > Silver > Gold > Platinum.
A laboratory test for hydrogen can be performed using a burning wooden splint. The burning wooden splint goes 'pop' if it is placed in a test tube filled with hydrogen (the flame ignites the hydrogen which makes a loud sound from burning explosively).
Salts produced from the reactions of acids and metals are named in the following way: the first part of the name derives from the metal that was used and the second part of the name derives from the acid that was used. Salts derived from hydrochloric acid (HCl) have chloride as the second part of their name, salts derived from sulphuric acid (H₂SO₄) have sulphate as the second part of their name and salts derived from nitric acid (HNO₃) have nitrate as the second part of their name. An example of a common salt is sodium chloride (NaCl) (table salt).
Other, less common, acids could also be used in the discussion. For example, salts derived from hydrobromic acid (HBr) have bromide as the second part of their name and salts derived from phosphoric acid (H₃PO₄) have phosphate as the second part of their name.